Elite Four and Champions
Below are the Elite Four and Champion(s) featured in the Unova region. They are listed in no real specific order as Unova, for the first time ever, has no official order that is required when facing the members of the Elite Four. That said, the true Champion, Alder, will not be available for battle until long after you have beaten the main story-line...
First you'll have to defeat the pseudo-champions N and Ghetsis (listed below as Ghetsis). As with Unova's Gym Leaders, the considerations for the Elite Four+Champion are unique and unlike any previous region...
Click the leader's name to visit the page detailing that Elite member in Black and White. Links are also provided to head directly to details about rematches with each member of the league, assuming a rematch is available later in the game.

Elite Shauntal
View info on the Elite Four member, Shauntal. Your first, or however you decide to order them, Elite battle will focus on Ghost type Pokémon. For the initial match levels range from 48-50.
Click here to view rematch info for this battle. Levels for this battle range in the 71-73 area.

Elite Grimsley
View info on the Elite Four member, Grimsley. Your second, or whichever order you battle them in, Elite battle will focus on Dark type Pokémon. For the initial match levels range from 48-50.
Click here to view rematch info for this battle. Levels for this battle range in the 71-73 area.

Elite Caitlin
View info on the Elite Four member, Caitlin. Your third, or however you want, Elite battle will focus on Psychic type Pokémon. For the initial match levels range from 48-50.
Click here to view rematch info for this battle. Levels for this battle range in the 71-73 area.

Elite Marshal
View info on the Elite Four member, Marshal. Your fourth, or however you want, Elite battle will focus on Fighting type Pokémon. For the initial match levels range from 48-50.
Click here to view rematch info for this battle. Levels for this battle range in the 71-73 area.

Pseudo-Champion and Ghetsis
View info on Pseudo-Champion and Ghetsis. Your last Elite battle (the first time through) and both characters have fairly well-balanced teams/Pokémon. For this match levels range from 52-54.
There is no rematch for this battle.

Champion Alder
View info on the League Champion, Alder. Alder's team/Pokémon, as with the pseudo-champion and Ghetsis, is fairly well-balanced. For the initial match levels range from 75-77.
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